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TECHNOGENIC INHALATORY SIZE PARTICLES FROM GROUND ATMOSPHERE OF URBAN AND RURAL ENVIRONMENT – COMPARATIVE ELEMENTAL AND MORPHOLOGICAL ANALYSIS

Valeria B. Stoyanova, Tsenka I. Tsacheva, Miko V. Marinov

Institute of Physical Chemistry, Bulgarian Academy of Sciences, Sofia 1113, Bulgaria

Received: 25.09.05; Cited: 28.01.06

Abstract: An attempt is done for qualitatively and quantitatively comparison of the levels of technogenic pollution in the low atmosphere by applying of express electron microprobe analysis (SEM and EDX) and SEI and BEI mode of image. Dust collected by free sedimentation on polished carbon substrates from several urban and rural regions of Bulgaria was investigated. The obtained by EDŐ-ray integral spectra of the elemental contents reflect the background soil-mineral influence. Size distribution, morphological characteristics and  individual elemental spectra of particles smaller than 10 mm (PM10), known as risk inhalant, were studied in detail. Express distinguishing of technogenic from natural PM10 was developed by viewing them in BEI-COMPO image regime as bright objects. Their individual elemental spectra show the amount of heavy elements (Pb, Ba, Fe, Cu, Zn, etc.) These technogenic PM10 are classified in a few principal categories (cluster groups) and their partial surface concentrations are compared and discussed with respect to ground urban and rural pollution in Bulgaria.

Key words: Atmospheric Pollutants, PM10, Technogenic Inhalatory Particles, Pb, SEM, EPMA

Pages 1-24

Relationship between germination and electrical conductivity of Pinus brutia und Pinus pinea seeds

Ioannis A. Takos, Georgios K. Varsamis, Theodora P. Merou, Elissavet P. Konstantinidou

and Spyridon A. Galatsidas

Technological Educational Institute (T.E.I.) of Kavala, Department of Forestry &Natural Environment Management, 66100 Drama, Greece. E-mail: itakos@teikav.edu.gr

Received: 15.02.06; Cited: 28.02.06

Abstract: In this paper electrical conductivity and its relationship to germination percentage of Pinus brutia and Pinus pinea seeds of 1997, 2002 and 2003 collection years that were examined in 2005, are presented. In both species seeds of 1997 collection year presented no germination, while their electrical conductivity measurements after 240 hours, being expressed in dry seed weight, were 67.39 μS*g-1 for Pinus pinea and 194.47 μS*g-1 for Pinus brutia respectively. On the contrary, in both species seeds of 2002 and 2003 collection years, showed high germinability, which was not statistically different between collection years, with the respective germination percentages being 93% and 100% in Pinus pinea and 60.5% and 57.5% in Pinus brutia seeds. Similarly, their electrical conductivity, after 240h, was not statistically different between collection years and presented low values which were 8.38 μS*g-1 and 8.57 μS*g-1 in Pinus pinea and 23.97 μS*g-1 and 31.07 μS*g-1 in Pinus brutia seeds. The correlation between seed electrical conductivity and germination percentages was high. Although, in the present research, the conductivity testing lasted 240h, it could be much shorter, as the correlation coefficient was high from the beginning of the measurements. Thus, the duration of the conductivity testing can be 36 h for the P. brutia seeds and 168 h for the P. pinea seeds. 

Key words: electrical conductivity, germination, Pinus brutia, Pinus pinea, seed

Pages 25-34

Sustainable neighbourhoods: Assessment tools for renovation and development

Andreas Blum*, Marcus Grant**

*Leibniz Institute of Ecological and Regional Development (IOER)
Weberplatz 1, 01217 Dresden (D)

**University of the West of England (UWE)
Frenchay Campus, Coldharbour Lane, BS16 1QY, Bristol (UK)

Received: 15.02.06; Cited: 28.02.06

Abstract: The main results of the of the European FP5 Project “Sustainable Renovation of Buildings for Sustainable Neighbourhoods” (HQE²R – Haute Qualité Environnementale et Economique Réhabilitation; http://hqe2r.cstb.fr) are a general approach and the necessary tools to promote sustainable development and quality of life on the crucial and likewise challenging level of urban neighbourhoods: The HQE²R toolkit for sustainable neighbourhood regeneration.

This paper presents one of the major parts of the toolkit, the “HQE²R index and directory of assessment tools for the built environment”. After a short section on “What is a sustainable neighbourhood”, theoretical basics of the assessment of urban development projects are presented. The third part gives a brief description of selected examples of existing European evaluation approaches and certificates for sustainable construction on building and neighbourhood scale including an introduction to the HQE²R tools “INDI” (INDicator based sustainability Impact assessment), “ENVI” for environmental concerns and “ASCOT” for the estimation of sustainability related construction costs. The paper concludes with a summary of the assessment experience made within the demonstration neighbourhoods being partner within the project.

Key words: neighbourhood, regeneration, sustainability, assessment, evaluation

Pages 35-52

POST FIRE RECOVERY IN A MEDITERRANEAN CONIFER ECOSYSTEM

Ioannis D. Mitsopoulos1, Georgios S. Efthimiou2

1Laboratory of Forest Protection, School of Forestry and Natural Environment, Aristotle University of Thessaloniki, P.O.Box: 228, 54124, Thessaloniki, Greece.

2Forest Research Institute, NAGREF, Thessaloniki, Greece.

Received: 28.02.06; Cited: 10.03.06

Abstract: Post fire seedling establishment and fuel dynamics were investigated in a Mediterranean conifer ecosystem dominated by Pinus halepensis Mill. (Aleppo pine) in central Greece between 5 and 15 years after fire. Seedling establishment was analyzed according to stem density, height and diameter at ground base. One-way ANOVA was used to test vegetation structure differences among sites and Duncan multiple range tests for mean pair comparisons. The results showed a rapid increase of height and mean diameter at ground base, as early as the 10th and the 15th post fire year respectively. A relatively high initial pine seedling density after fire followed by a decrease during the 10th and 15th post fire year respectively is shown. Fuel components were separated into size classes and regression equations that estimate fuel load by diameter class were derived. This series of equations provide quantitative fuel attributes for use in fire behavior models and fire management in Aleppo pine stands.

Key words: Wildland fire, post fire recovery, seedling establishment, fuel dynamics, Mediterranean Basin.

Pages 53-63

EFFECTS OF THE KOLA AIR POLLUTION SOURCES TO AIR QUALITY AND ENVIRONMENT IN NORTHERN FINLAND

Jussi Paatero, Ulla Makkonen, Seppo Haarala, Outi Tolonen-Kivimäki, and Timo Salmi

Finnish Meteorological Institute

P.O.Box 503, FI-00101 Helsinki, Finland

Received: 28.02.06; Cited: 10.03.06

Abstract: The mining and metallurgical industry at Kola peninsula, north-west Russia is the most important source of air pollution next to Norilsk in the Arctic. The gas- and particle-phase pollutants have a serious impact to the atmosphere and biosphere at Kola peninsula and, to a lesser extent, in northern Finland. The effects include acidification, ecotoxicological effects, and even human health effects. The Finnish Meteorological Institute (FMI) has monitored air quality, e.g. sulphur dioxide, airborne sulphate and deposited trace metals and sulphate in several monitoring stations in northern Finland close to the Russian border to study these effects.

Key words: Kola peninsula, metal smelters, emissions, air pollution

Pages 64-73

LOCAL SOIL CONDITIONS OF THE AREA BETWEEN THE GULF OF IZMIT AND LAKE SAPANCA

KURTULUS C1., BOZKURT A2., ENDEŞ H.1

KOCAELI UNIVERSITY, ENGINEERING FACULTY, Kocaeli-Izmit, TURKEY

Received: 28.02.06; Cited: 10.03.06

Abstract: The investigation area is located between the Gulf of Izmit and Lake Sapanca in the north-west of Turkey. Three sedimentary units of different age are placed in this area. These are the Quaternary and Pliocene sediments and the Pre-Quaternary rocks. The borehole data indicated that the Quaternary sediments are formed of alternating silty clay, gravely silty clay and clayey silt whilst the Pliocene sediments consist of conglomerate, sandy silty clay. The Pre-Quaternary sedimentary rocks are formed of claystone, sandstone, marl and siltstone.

Geophysical survey and geotechnical tests have been conducted in this region to determine the engineering soil parameters and soil classes. The Attarberg limits of the Quaternary sediments are obtained as LL=38.0-40.72%, PL=18.0-20.33%, PI=18-20.39%, W=20-22.64%, Cc=0.26-0.89, Ic=0.86-0.89, and that of the Pliocene sediments are determined as LL=41.2-42.72%, PL=21.4-22.34%, PI=20.09-22.31%, W=22.76-23.69%, Cc=0.28-0.31, Ic=0.91-0.24. The soil classes of the Quaternary sediments are figured out as CL, CH, and that of The Pliocene sediments are obtained as SM, ML. The RQD values of the Pre-Quaternary sedimentary rocks are determined as TCR=60-75% and RQD=75-90%.

The P-and S-velocities are obtained as 881-895 m/s and 392-398 m/s for the second layer of the Quaternary sediments, 840-960 m/s and 350-400 m/s for the second layer of the Pliocene sediments, and 1408-1539 m/s and 687-751 m/s for the second layer of the Pre-Quaternary rocks.

The Bearing capaticies are determined for the Quaternary sediments 4.5-4.52 kg/cm2, for the Pliocene sediments 3.75-4.14 kg/cm2, and for the Pre-Quaternary rocks 6.78-7.26 kg/cm2.

Salty water intrusion was detected in the sediments near the east of the Gulf of Izmit having the resistivity value of 3 Wm.

Pages 74-87

EVALUATION OF 55Fe AND 63Ni DEPOSITION LEVELS IN THE IGNALINA NPP ENVIRONMENT USING MOSSES AS BIOINDICATORS

Arūnas Gudelis, Rūta Druteikienė, Benedikta Lukšienė, Rasa Gvozdaitė

Institute of Physics, Savanorių Ave. 231, LT-02300 Vilnius, Lithuania

Received: 28.02.06; Cited: 10.03.06

Abstract:  The Ignalina NPP with two RBMK-1500 reactor units operates in Lithuania for more than 20 years. It is located on the shore of Lake Drūkšiai the water of which is used for technological applications of the plant. An impact to lake environment had been extensively investigated during the campaigns in 1989-1993, when gamma-ray emitting radionuclides (54Mn, 58Co, 59Fe, 60Co, 95Zr, 95Nb, 134Cs, and 137Cs) were determined in soil, sediments, meadow and water plants, and in 1996, when moss samples had been analyzed by gamma-spectrometry. Only 137Cs and 60Co were detected in moss samples, with the maximum deposition level of the latter of 30 Bq/m2.

Recent investigations into the artificial radionuclides content in both operational and industrial waste originated at the Ignalina NPP involved determination of so called “difficult-to-measure” nuclides including activation products, such as 55Fe and 63Ni.

The aim of this work is to evaluate the deposited activities of 55Fe and 63Ni in the vicinity of the source by experimental methods. For this task, moss and soil samples were taken from 10 locations around the Ignalina NPP in November 2005. Non-destructive analysis by HPGe gamma-spectrometry was followed by radiochemical separation and liquid scintillation counting for simultaneous determination of 55Fe and 63Ni from the single sample aliquot.

Key words: Ignalina NPP, RBMK-1500, moss, liquid scintillation counting, 55Fe, 63Ni, gamma-spectrometry, 60Co, 137Cs.

Pages 88-97

ECOLOGY AND STRATEGIES OF DESICCATION-TOLERANT PLANTS AND VEGETATIONS

Tuba, Z.1,2

1Department of Botany and Plant Physiology and 2Departmental Research Group of Hungarian Academy of Sciences, Faculty of Agricultural and Environmental Sciences, Szent István University, H-2103 Gödöllő, Páter K. u. 1., Hungary

Received: 28.02.06; Cited: 10.03.06

Abstract: The desiccation-tolerant (DT) plants are poikilohydric and capable of surviving the loss of at least 90-95 % of their cell water content. DT plants are important constituents of many ecosystems from the arctic (lichen and moss vegetations) to the tropics (lichen, moss and flower vegetations) regions and large pools of nutrients and carbon can be found in the DT vegetations of these ecosystems, and therefore significant aspects of ecosystem function depend on their ecophysiological responses, production and turnover pattern. In the tropics the inselbergs as ecologically isolated habitats from the surrounding areas are evolutional centers of the flower DT plants and vegetations, which are among the key ecosystems of plant taxonomical and functional diversity. On inselbergs the flower DT vegetations cover globally significant areas with globally significant amount of biomas and C-pool. The DT plants do have a direct practical significance, also: to develop crops that are tolerant of the harmful effects of drought. The paper will summarize the recent development in our understanding of ecology and strategies of DT plants and vegetation.

Key words: desiccation-tolerance, poikilohydry, inselberg, tropical/subtropical, poikilochlorophylly, desoccoplast

Pages 98-105

Preparation of hydrophobic  Pt-catalysts for tritium removal from NUCLEAR  efFluents

Irina Popescu, Gh. Ionita, D. Dobrinescu and I. Stefanescu

Institute for Cryogenics and Isotopic Technologies, 4 Uzinei Street, Rm. Valcea, Romania, ipop@icsi.ro

Received: 28.02.06; Cited: 10.03.06

Abstract: Based on the long experience of the authors, in the preparation, testing and evaluation of the performances of hydrophobic catalysts, and based on the reviewed references, this paper presents up-to-date R&D activities on the application of the hydrophobic catalysts, in deuterium and tritium separation from nuclear effluents. Unlike the conventional hydrophilic catalysts, the hydrophobic catalysts kept a high catalytic activity and stability, even under the direct contact to liquid water or in presence of saturated humidity. A large diversity of catalyst types (over 100 catalysts) was prepared and tested in order to make feasible the hydrogen isotopes separation processes

The enrichment of deuterium and tritium by isotopic exchange between water and hydrogen, tritium removal from heavy water reactor and nuclear reprocessing plant, the cleanup of atmosphere and gaseous effluents by catalyzed hydrogen-oxygen recombination, are largely presented and discussed.

The objectives of the work are: (1) to provide a database for selection of the most appropriate catalyst and catalytic packing for above mentioned processes, (2) the designing and operation of reactor packed with hydrophobic catalysts,  (3) to evaluate the potentiality of hydrophobic Pt-catalysts in the deuterium and tritium enrichment

The merits of the hydrophobic catalysts are shown in comparison to hydrophilic catalysts. Some  suggestions concerning the deuterium and tritium enrichment by means of hydrophobic catalysts are also discussed.

Key words: hydrophobic catalysts, tritium removal.

Pages 106-114

RELATIONSHIP BETWEEN OZONE DOSE AND TEMPERATURE REGIME IN TWO FOREST ECOSYSTEMS

Nikolina Tzvetkova, University of Forestry, Sofia

Received: 28.02.06; Cited: 10.03.06

Abstract: The data, obtained by monitoring of air pollution and climatic factors at two forest ecosystems - natural coniferous stand of Đicea abies L. and Abies alba L. in station Yundola, and deciduous stand of Fagus sylvatica L. in station Vitinia was presented. An estimation of relationship between ozone dose and air temperature and radiation during the growth period of 2003 was established for the stations. The cumulative ozone dose during separate months of the growth period (AOT40) and air temperature fluctuation showed some peculiarities in coniferous and deciduous forest. These characteristics are discussed in relation to the dynamics of ozone concentrations and radiation regime in the ecosystems.

The results presented are part of Swiss-Bulgarian project “monitoring of Forest Ecosystems”

Key words: air pollution, cumulative ozone dose, air temperature, solar radiation, forest ecosystems.

Pages 115-124

 

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